Computer Chips Communicating With Light As computer chips get faster and faster moving information around them is getting more difficult, as sending information very fast electrically uses lots of energy. One solution is to use light to communicate, you can transmit far more information with much lower energy losses - this is actually how information is moved long distances, between mobile phone masts, across the atlantic etc. 23rd Sep 2006 A Strange Supernova is worrying cosmologistsA supernova is basically an exploding star, the explosion can be cause for a variety of reasons. A very important type is 1a, this is caused where an old star ember called a white dwarf is slowlyy aquiring matter from another star (probably a red giant), eventually it gets so heavy that it can't support itself and it collapses. In this collapse carbon and oxygen start to fuse together creating heavier elements ( almost all the heavy elements in the universe were made in supernovae), this releases an immense amount of energy and blows the star apart creating an explosion 5 billion times brighter than the sun. Unfortunately Andrew Howell has found what appears to be a type 1a supernova that is 2.2times brighter than the model says it should be possible to be. Maybe the star was spinning fast which allowed more matter to build up before it collapsed. This could mean that astonomer's have observed lots of supernovae that are actually at lot further away than was calculated and cosmolgists are going to have to look at their data, and possibly their conclusions very carefully. 23rd Sep 2006 Science Update - the Sharpest and the Fastest.Chelsea Wald and Bob Hirshon from AAAS, the science society
Bob - This week on Science Update, we'll talk about some ants that have set the world record for fastest-moving body part. But first, Chelsea reports on another world record - for sharpest object. Chelsea - The tip of the world's sharpest needle is a single atom of tungsten. I asked physicist Robert Wolkow of the University of Alberta what it would be like to hold it in my hand. Robert - It would be just like a sewing needle or a pin and you would see that it was very sharp but you wouldn't be able to see the end of it-it's so small it's invisible. And if you put it under the most powerful microscope in the world, you would only then just barely see the tip of it. Chelsea - Wolkow says they make these needles by exposing a normal needle made of tungsten to nitrogen gas and electricity. The gas and electricity interact with the end of the needle to pluck off atoms until there's only one left. Robert - It's kind of like sculpting. In a sculpture the final shape is already in the block of stone and the sculpture knows what to take away. Well, we're not sculptors, but we take away the atoms form the edge, leaving a tiny, tiny needle. Chelsea - Since it's so sharp, Wolkow says the needle could prove to be the best probe ever made for use in powerful electron microscopes. Bob - Thanks, Chelsea. A type of insect called the Trap - jaw ant has jaws that now hold the record for the fastest - moving self-propelled body part in the animal kingdom. But it's what they do with those super-speed jaws that's really interesting, according to University of Illinois entomologist Andy Suarez. Andy - These ants will use their mandibles not only to capture food, but to propel themselves off the ground, to escape threat or predators. Bob - Using a high-speed imaging system, Suarez found that the ants cock their jaws open against the ground and then snap them shut at close to 100 miles per hour. That's enough force for some pretty impressive flips and serious hangtime. Andy - In the field when they start jumping around, it's just a fraction of a second-they just pop up in the air and they're on the ground again. And when you can slow this down and dissect the movement, the kinematics, of what's going on, it's really quite beautiful-it's very acrobatic. Bob - Suarez says the ants probably first evolved the fast jaws to capture prey, but then repurposed the skill to escape becoming prey. Chelsea - Thanks, Bob. That's all for this week. Next week we'll discuss a new estimate of how many types of dinosaurs are still waiting to be dug up. Until then, I'm Chelsea Wald. Bob - And I'm Bob Hirshon, for AAAS, The Science Society. Back to you, Naked Scientists September 2006 The Science of Catalysts And Catalytic ConvertersDr Emma Schofield, Johnson Matthey Technology Centre
First of all, everyone uses the word 'catalytic converter' but what is a catalyst and why is it important? - A catalyst is a substance that makes a chemical reaction happen more easily. You can get some really stroppy reactions in which you want to rearrange the atoms in them to make something useful, but it's just not playing. The starting material just isn't interested into becoming the product that you want. IF you put the right catalyst into the reaction, you can make this reaction happen either more quickly or using a lot less energy. Often you have to go into high temperatures and pressures to get the reaction to work. - How do they do that? - Imagine that you've got yourself a beach cottage and the beach is about a mile away from your cottage. Between you and the beach there is this massive great mountain. You have several options for reaching the beach. One of them is that you put lots of energy into it, so you put lots of energy to walk up the mountain and down the other side. Not great. The second option is to walk all the way around the mountain but it takes a heck of a long time. But if someone's gone and dug a tunnel from one side to the other then you can get to the beach pretty quickly and with a lot less energy. This is exactly what a catalyst does. So the catalyst does for a chemical reaction what the tunnel does for you: it takes an alternative pathway that allows the reaction to happen a lot more easily. - And just like a tunnel, it's not used up in the reaction. It's available forever if you like. - Yeah and that's why you only need a very small amount of catalyst when you have a chemical reaction. Because although the catalyst is changed during the reaction, it's regenerated at the end of it. So each little atom or each little molecule of catalyst that's in there can go on a react with hundreds and thousands of millions of reactant molecules. - Sounds fantastic, but how do we find these things? Why isn't there a catalyst for everything? Why isn't there a catalyst for my homework? How do we discover the chemicals that do these clever jobs? - There are quite a lot of metals that are used as catalysts because there are two different types of catalysts: homogeneous catalysts and heterogeneous catalysts. In homogeneous catalysts, the reactants and the products are in the same phase. So if there are gases reacting, the catalyst will also be a gas. In heterogeneous reaction, the reagents are in a different phase from the catalyst. An example of homogeneous would be making plastic bags - high density polyethylene. The ethene and the catalyst are all going on in the same phase, in solution. That would be a homogeneous catalyst. In a heterogeneous catalyst, that would be carbon monoxide turning into carbon dioxide. That would happen on platinum metal. - They've got expensive tastes these things! - Platinum is very expensive but you often find that some of the most expensive metals turn out to be the best catalysts. - Why is platinum so good? What's special about the metal? How does it do what it does? - When people ask questions like this, a scientist's usual answer is: oh well, it's quantum. Actually it's to do with how well these gas molecules can stick to the surface. Platinum is very good at sticking molecules onto the surface of it. That's very important because that's where the reaction actually happens. The other thing that platinum is good for is, well, when you have a molecule, the atoms in the molecule are stuck together with chemical bonds, which are electrons. Platinum is very good at rearranging these electrons and allowing the molecules to turn into something else. Again, forming this alternative pathway by which a chemical reaction can happen. - So if you could zoom in to the surface of the platinum, what would it look like to make it so sticky and that things like it? - We always imagine it as lots of little balls stuck next to each other. One of the aims of being a catalyst chemist, which is what I am, is to try and make as much surface as possible. So we have our tiny little pieces of platinum which are stuck onto a ceramic support. We want as much platinum on the surface and as little platinum in the middle of these balls as possible. The platinum is part of the periodic table which has lots of d-orbitals, and it's these magic d-orbitals that makes it so good at catalysis and making things stick to it. So it very easily forms bonds with lots of different types of molecule. - And it brings them together in just the right way that they want to get married or do whatever you want them to do. - And provides them with a route which requires so little energy that it can happen essentially spontaneously or with very little energy on the metal's surface. - Ok so turning now to what comes out of your exhaust pipe, how does a catalytic converter on a car actually work? What are they doing? - The catalyst on a catalytic converter is essentially a can which is next to the engine. What it does is it purifies the exhaust gases. If it was ideal, we'd just get carbon dioxide and water out when fuel was burnt. - I'm sure people would argue that it would be ideal if we just had water and burning hydrogen, which is what Fraser is going to be talking to us about in a minute. - The problem being that you put fuel in at the beginning and you can destroy atoms as you go along. But what we also get out is carbon monoxide, which is a poison and binds so strongly to the blood that you can't bind oxygen anymore. There are also what's called NOx gases, which are oxides of nitrogen responsible for acid rain; and hydrocarbons which come together with NO-x to form smog. This is why in the 1970s Los Angeles got buried under this cloud of photochemical smog and what triggered all of the legislation about car pollutants. Also what comes out are particulates, which are essentially soot. This is linked with respiratory illnesses as well as cancer. So we obviously don't want these coming out of the backs of our cars. We need to put the catalytic converter between the engine and the exhaust pipe to catch these things as they go out. Inside the catalytic converter we have the monolith and the metal. The monolith is a ceramic and it's a honeycomb with a very large surface area and it's coated to give it an even greater surface area. If you spread it out it would cover about three football pitches. On the channels of this monolith you have little globules of the metal platinum, palladium, rhodium in various mixtures depending on whether you're a petrol or a diesel car, and these are so small that we call them nanoparticles. This is what we were talking about before. As these gases go past, which is a very quick reaction, it goes from the engine through the catalytic converter in less than a tenth of a second. - So it must be very fast. - Yes and it wouldn't happen normally unless there was a catalyst there. - So how much of the gases does the catalytic converter scavenge or convert? Does it do the lot? - It causes about a 90% decrease in the amount of pollution coming out, and what you mostly get out of the other end is nitrogen, water and carbon dioxide. - So it does a good job but there was a motivation for people to stop using leaded fuel because it makes your brain rot and causes dementia but also lead's quite toxic to catalysts. - Exactly. If you think about these little metal particles, the lead will stick onto the surface of them. The more you reduce the amount of surface there is, the less chance these pollutant gases have of sticking to the surface and making the catalyst catalyse. - So it's better to do without lead if we can for more reason than one. - It's better to do without lead and it's better to do without sulphur in petrol too, because sulphur is responsible, or used to be responsible when we had high sulphur petrol, for this eggy smell some people associate with catalytic converters. Now there's less sulphur in fuel, this is much less of a problem. - Now Emma, it's impossible to miss your t-shirt and on the subject of noisy engines, I was wondering if this was what we're talking about! It says NOISE. What is NOISE and why are you here today? - NOISE is the New Outlooks In Science and Engineering campaign. It's a group of young scientists who are there to give an alternative image for what scientists are like. Chris, when you think about the stereotype of a scientist, what is it that springs to mind? - Glasses more powerful than the Hubble space telescope, shocking teeth, 1960s get-up and muttering unintelligibly in a way that no-one can understand. - And the words fun and dynamic don't really feature in those descriptions. - But that's why people listen to the Naked Scientists! - And that's why NOISE is there. We need to change this. We're the new generation of young scientists and we have a website www.noisemakers.org.uk where there's this whole group of scientists that do lots of fun science that we want to tell people about. We have a snowboarding physicist and we have somebody who does robotics who is a scuba diver. The idea is to point out to people, especially kids who are thinking of going to university, that there's more to being a scientist than a white coat. - September 2006 HydrogenA FUEL FOR THE FUTURE? - Professor Fraser Armstrong, Oxford UniversityDave - With us this evening we have Fraser Armstrong from Oxford University. You work on fuel cells - can you explain what a hydrogen fuel cell is? Fraser - Well first of all hydrogen is a energy carrier much like petrol or any sort of oil or coal. But it's a very different type of energy carrier because it's a gas, and it's not necessarily a very convenient energy carrier because hydrogen is a gas all the way down to something like 20 Kelvin. This is about minus 250 degrees Celsius. So it's not a very convenient fuel, but when combined with oxygen, hydrogen and oxygen make a bang together and give off water. Chris - The people on the Hindenburg knew a bit about that. Fraser - Well they did unfortunately, yes. Hydrogen is a very good and light fuel; that's why it's used in spacecraft even if it's not very useful in terms of being able to transport it efficiently. Chris - Just as aside on the Hindenburg disaster, it was actually a bit of a myth that it was the hydrogen, although that didn't help. When the Germans built it they thought it looked nice as a silver colour because it showed up the Nazi swastika very nicely. In order to get that colour they sprayed it with aluminium, and aluminium particles burn beautifully. Fraser - That was a bad choice. Dave - So what does an actual fuel cell look like? Fraser - Well a fuel cell consists of two electrodes: one on which hydrogen is oxidised to protons. Of course, as we've just heard from Emma, this needs a catalyst and the catalyst in this case is generally platinum or platinum with other precious metals. Hydrogen is oxidised to protons and at the other electrode, oxygen is reduced to oxide. The oxide and the protons combine to form water. We find that we have a large amount of energy produced from this, and it's the same amount of energy as would be produced if we deliberately burned hydrogen and oxygen and got an explosion. Now the energy is converted directly into electricity, which can be used to power devices. Dave - I guess there's a problem if the hydrogen gets on the wrong side and the hydrogen gets on the wrong side. How do you normally solve that problem? Fraser - Well normally the anode and the cathode as the two electrodes are called, are separated by a membrane called the proton exchange membrane. Hydrogen is directed at one of the electrodes and air is directed at the other electrode. Generally there is very little in the way of cross-over, which is the mixing of gases. Chris - Since this show is about catalysts, I've got to ask, what is the catalyst that's doing this in your fuel cells? Fraser - In the conventional fuel cell, which is called the proton exchange membrane fuel cell, the catalyst is platinum, as we heard from Emma. My research group is investigating the possibility of other types of catalysts for this type of technology, particularly ones that are based on enzymes that occur in microbes. These particular enzymes do not of course contain platinum at their active centre but contain other elements that are much more familiar: in particular iron and most often nickel as well. Dave - I guess that this is a big advantage because if you powered all the cars with platinum fuel cells you'd run out of platinum quite quickly. Fraser - Well either we'd run out or the price would go up and up. There's always a good point to having catalysts that are on the market. Chris - So why do bacteria need to be able to do this with hydrogen? Why do we need to do that? Fraser - Very interestingly the bacteria have used hydrogen as a fuel for over 2.5 billion years. If we go back in time to the earliest life forms, at the particular time there was no oxygen on the Earth and many microbes would use the proton as an oxidant. Of course, when one reduces a proton, we obtain hydrogen. So many bacteria have the ability to make hydrogen from protons, that is, from water. Equally, other bacteria have the ability to use hydrogen as a fuel. So there's a kind of cycling that's possible in the microbial world. Chris - Is it possible for us to co-opt this efficiently enough to run our cars though? Fraser - No I don't see this ever running cars because as it stands at the moment, the problem with enzymes is that they're not designed to last forever and they're not designed to withstand very high temperatures and reaction conditions. However, we can learn a considerable amount by studying the active sites of the enzymes and the molecular structure. Chris - In other words the business end that does the catalysis. Fraser - Yes the business end at which catalysis occurs. Chris - And what, you'd hope to make a model of that or reproduce that more stabley? Fraser - For the purposes of high energy orhigh power, it may be possible in the future to make catalysts which are alternatives to platinum that use the chemistry of the active sites of enzymes as we currently understand them. It may also be possible to actually use enzymes themselves for power production, which is much less demanding than the automotive industry. Dave - So the advantage of your design with the enzymes is that you don't need to keep the oxygen separate any more. Fraser - In principle that may be quite correct. It is possible to mix hydrogen and oxygen to get non-explosive mixtures. However, the amount of hydrogen that one requires for this is less than 4% in air in order to avoid hazardous mixtures. September 2006
White bread and the wonder of enzymesUse enzymes in your mouth to break down bread in front of your very taste buds. What you need
What to Do
What may HappenAs you chew the bread, you may have noticed that it slowly tastes sweeter. Particularly the juice that is coming out. What is going on?Foods like bread, rice and potatoes are foods that are mostly made of starch. Starch is a molecule that plants make in order to store sugar. It consists of long chains of glucose (some of them branch). In your saliva you have an enzyme called amylase, this will cut up the large starch molecules at random until you are left with sugars made of 1,2 or 3 glucose molecules long (glucose, maltose or dextrin).
Starch doesn't taste sweet, but glucose and maltose do, so as you chew the bread it will slowly become slightly sickly sweet. Why do plants make starch in the first place?All living things are made up of cells these are surrounded with membranes which will let water pass through them but not larger molecules such as salt or sugar. If there are more salt or sugar molecules on one side of the membrane than the other, water is pulled towards the salt/sugar - this is called osmosis. This is why slugs shrivel up if you sprinkle salt on them, all the water is sucked out of them. Plants convert water and carbon-dioxide into glucose using the energy from the sun. If the plant is doing particularly well it will produce huge amounts of glucose in it's cells. This will cause water to be pulled into the cell. The problem is that this will happen until the cell explodes.
The solution is for the plant to glue all the sugar molecules together into a starch molecule, which just being one molecule rather than thousands will suck in water much less by osmosis, reducing the problem hugely.
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