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Author Topic: How would I answer this question? [salts]  (Read 6487 times)

Offline danica_aku

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How would I answer this question? [salts]
« on: 16/05/2006 11:59:15 »
What is the pH of 0.100 M sodium phenolate, C6H5ONa, the sodium salt of phenol?[xx(][xx(][xx(]

Please help me...


 

Offline Cut Chemist

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Re: How would I answer this question? [salts]
« Reply #1 on: 16/05/2006 20:33:35 »
Henderson Hasselbach Equation-

pH = pKa - log ([HA] / [A-])

HA would be the OH form
and A- would be the O- form

0.100 mols/ liter of phenolate anion (O- form) from dissolving the salt

look up Pka of phenol

pH = -log [H+]
 

Offline danica_aku

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Re: How would I answer this question? [salts]
« Reply #2 on: 20/05/2006 06:20:59 »
tnx a lot!:)
 

Offline DrDick

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Re: How would I answer this question? [salts]
« Reply #3 on: 25/05/2006 20:12:03 »
H-H doesn't work for this problem.  You need to be near the buffer region, where the phenoxide and phenol concentrations are within a couple orders of magnitude.

For this problem, you first need to calculate pKb of phenoxide, then Kb, then make an ICE table for the reaction:

    NaC6H5O + H2O <==> HC6H5O + NaOH
I    0.100                0       0
C      -x                +x      +x
-------------------------------------
E    0.100-x              x       x
     ~0.100

Kb = [HC6H5O][NaOH]/[NaC6H5O] = x^2/0.1
x = [OH-]
Once you find [OH-], you should be able to find pH pretty easily.

DrDick
 

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Re: How would I answer this question? [salts]
« Reply #3 on: 25/05/2006 20:12:03 »

 

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