Naked Science Forum

Non Life Sciences => Geology, Palaeontology & Archaeology => Topic started by: jmcef on 08/05/2018 23:25:51

Title: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 08/05/2018 23:25:51
hello,

i have some stones, found in a beach in europe. they are pretty common in the water as well.  they look like a highly corroded piece of metal, but they are stones and not magnetic (so unlikely to be just that)


* stones.jpg (265.37 kB . 1664x597 - viewed 6165 times)

any info to help identify them would be greatly appreciated

thanks
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: Kryptid on 09/05/2018 02:46:23
It would be helpful if you could determine some of its basic properties. Can glass scratch it? What about steel? Can you cut a piece in half to see what it looks like on the inside? What color is its streak? Can you measure the density?
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 09/05/2018 03:00:04
thanks for the reply, they can be scratched with a pointy metal object with enough force and depending on stone and area, with glass not so easily done. the inside is similar to the outside.  They are relatively heavy for their size.

When you see one you would think that its a badly corroded piece of metal, but its a stone so if it was a corroded metal it would just turn into dust.

thanks for any input you might have :)
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: Kryptid on 09/05/2018 03:12:41
Here's a tip on how you can get a numerical measure for the density: get a measuring cup and fill it up to any given level you want to (say, 100 mL). Then put one (or even all) of your pieces into the cup and see how much the water level increases. That will tell you what the total volume of material is. Then you can use a kitchen scale to measure the mass of that same material (preferably in grams). Once you get that number, you can divide the mass by the volume to get the density (in grams per milliliter, which is the same as grams per cubic centimeter).

Here is a list of minerals based on their density. It would work as a good starting point: https://www.engineeringtoolbox.com/mineral-density-d_1555.html (https://www.engineeringtoolbox.com/mineral-density-d_1555.html)

When it comes to the hardness, I guess your next step is to see if the mineral itself can scratch glass or steel. If it can scratch glass, then it should be about the same hardness as glass (5.5 on the Moh's scale). More information can be found here: http://www.oakton.edu/user/4/billtong/eas100lab/hardness.htm (http://www.oakton.edu/user/4/billtong/eas100lab/hardness.htm).

Have you tested the color of the streak yet? Maybe you could also test for fluorescence under a blacklight.
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: RD on 09/05/2018 17:07:19
i have some stones ... look like a highly corroded piece of metal, but they are stones ...

Iron stone (https://www.google.com/search?tbm=isch&q=ironstone%2Bmineral) ? ...


* Unknown Versus banded-IronStone.jpg (39.89 kB . 773x215 - viewed 5234 times)

https://en.wikipedia.org/wiki/Ironstone (https://en.wikipedia.org/wiki/Ironstone)

Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 09/05/2018 17:14:59
thanks for the feedback. The appearance/colors is somewhat similar to ironstone but its not it. If its relevant, its also not magnetic. its volume is 2.8cm3 (but my measurements might not have been too accurate)

it was gathered from the island of Malta, was found in some lost beach but others can be found in different areas of the island

thx
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: chris on 10/05/2018 08:09:13
Maybe @Bass can help?
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: guest45734 on 10/05/2018 12:28:10
it was gathered from the island of Malta, was found in some lost beach but others can be found in different areas of the island

The Maltese Islands are made up of 5 different rock types. These are namely; Upper Coralline Limestone, Greensand, Blue Clay, Globigerina Limestone and Lower Coralline Limestone.

How much do the stones weigh?

Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: chiralSPO on 10/05/2018 14:33:36
If the rocks appear corroded, perhaps you can use that to your advantage and study what corrodes them?
If you're willing to do some destructive sampling, I recommend submerging a small stone in vinegar (5% acetic acid). If bubbles begin streaming out, it is probably carbon dioxide, indicating a carbonate rock like limestone (though there are many carbonate minerals). There are ways to confirm that the gas is CO[sub2[/sub]. If it does react vigorously with the vinegar, I recommend letting the reaction go until everything that can dissolve has--there might be some other materials included in the stone.

You could also try putting a stone in liquids such as hydrochloric acid (sold in hardware stores for removing rust stains), bleach (sodium hypochlorite) and lye (sodium hydroxide). You can learn quite a bit about the composition based on what it reacts with/dissolves in and other observations--if it smells like rotting eggs when treated with hydrochloric acid, it probably contains sulfides, if it dissolved in hydrochloric acid or ammonia and produces a colored solution, the stone might contain transition metals like iron (yellow to brown solutions), cobalt (pink/purple/blue) nickel (yellow to green), copper (blue to green) etc.
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 10/05/2018 15:11:13
it was gathered from the island of Malta, was found in some lost beach but others can be found in different areas of the island

The Maltese Islands are made up of 5 different rock types. These are namely; Upper Coralline Limestone, Greensand, Blue Clay, Globigerina Limestone and Lower Coralline Limestone.

How much do the stones weigh?

thanks for the message. i am familiar with the Maltese rock types but the stones in questions are nothing related to them. they are found mainly in some beaches (with the other pebbles) so they are pretty hard, the once in the photo can easily stay in the palm of a hand (so we are not talking large rocks)

thanks

Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: guest45734 on 10/05/2018 16:42:16
i am familiar with the Maltese rock types but the stones in questions are nothing related to them. they are found mainly in some beaches (with the other pebbles) so they are pretty hard, the once in the photo can easily stay in the palm of a hand (so we are not talking large rocks)

Could the rocks be Clinker from old furnaces?

Another possibility is that the stones are Fubarite.
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 10/05/2018 17:09:54
Clinker

theirs some distant similarities to some brown Clinker but i think its unlikely because they are found in different remote areas on the island, underwater too, so unlikely of being anything man made - apart from the fact that they are very hard and dense, resembling beach pebbles. at first glance i think they distantly resemble brown meteorites (but they are not, they are not attracted to magnets)

i have always wondered what they are because they are particularly different from the typical pebbles


thanks
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 10/05/2018 18:05:01
here is a video which might show the items in questions much clearly : https://www.dropbox.com/s/nvolqhkxbgfqtui/20180510_161455.mp4?dl=0
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: Bass on 10/05/2018 18:47:54
Based on your descriptions and the photos/video, my guess would be iron oxides, probably a mix of goethite and limonite. Possibly secondary hematite, but the colors don't quite look right.
Secondary (from weathering) iron oxides are common in many limestone terrains, and most limey rocks contain iron at different concentrations. Common iron carbonate rocks are siderite and ankerite.
Do any of the rocks effervesce (bubble) when you put acid on them? Sometimes you have to scratch or grind down a bit of powder before you get a reaction.
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: chris on 10/05/2018 21:39:49
Do any of the rocks effervesce (bubble) when you put acid on them?

Is this to test for limestone?
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: jmcef on 11/05/2018 01:04:28
hematite

thanks for the reply, i am aware of iron in milestones but normally they iron in them is brittle - not as dense and sturdy as these rocks.

when put in vinegar theirs some bubbles, but very little and from the surface material on the stone (so i think the bubbles might be unrelated to the material)
Title: Re: Resembling corroded pieces of metal, what are these stones?
Post by: Bass on 15/05/2018 19:17:22
Use of acid is to test for the presence of carbonates (limestone is a carbonate rock). Ankerite, siderite and dolomite do not bubble much when acid is applied- at times you need to powder the rock first before it will bubble, or apply acid that has been heated.
Secondary iron oxides can be brittle and easily broken or crumbled, or can be quite dense- depending on how they formed.