Naked Science Forum

Non Life Sciences => Technology => Topic started by: Tintin_Triton on 28/09/2009 07:46:05

Title: Could we make better fuels for Formula 1?
Post by: Tintin_Triton on 28/09/2009 07:46:05
I was watching the Singapore Grand Prix yesterday, and suddenly this thought came into my mind : What if we can provide some better fuels than they use there? I was looking towards Hydrogen, but then it occurred to me that it does not provide enough power per litre.

Can anyone tell me of the fuels that can be less polluting, and yet more efficient than petrol?

Thanks!
Title: Re: Could we make better fuels for Formula 1?
Post by: Turveyd on 28/09/2009 23:46:04
Liquid Oxygen would be the best fuel and it's clean by product being water.

Producing the Liquid Oxygen and super cooling it in the first place likely takes a lot of energy ruining the green part.



Title: Re: Could we make better fuels for Formula 1?
Post by: Karsten on 29/09/2009 00:09:18
Oxygen burns?
Title: Re: Could we make better fuels for Formula 1?
Post by: Don_1 on 29/09/2009 09:00:41
"Can anyone tell me of the fuels that can be less polluting, and yet more efficient than petrol?"

If I knew the answer to that, I would be rich beyond my wildest dreams. So I wouldn't be telling you, or anyone else, anything about it.

Does anyone know where the starship Enterprise gets it's dilithium crystals from?
Title: Re: Could we make better fuels for Formula 1?
Post by: Tintin_Triton on 29/09/2009 09:42:22
"Can anyone tell me of the fuels that can be less polluting, and yet more efficient than petrol?"

If I knew the answer to that, I would be rich beyond my wildest dreams. So I wouldn't be telling you, or anyone else, anything about it.
Does anyone know where the starship Enterprise gets it's dilithium crystals from?
LOL....
That is true. But it just came into my mind to use hydrogen, highly compressed one; through the use of solar cells.
Hydrogen can readily burn, and producing it is easy! 
Title: Re: Could we make better fuels for Formula 1?
Post by: Tintin_Triton on 29/09/2009 09:44:09
Also, did anyone see Iron Man the movie? His Arc Reactor is the answer to all of our power woes!
Title: Re: Could we make better fuels for Formula 1?
Post by: peppercorn on 29/09/2009 12:47:57
"Can anyone tell me of the fuels that can be less polluting, and yet more efficient than petrol?"

If I knew the answer to that, I would be rich beyond my wildest dreams. So I wouldn't be telling you, or anyone else, anything about it.
Well, you need to add one more prerequisite to that:
Less polluting and more efficient for a similar large-scale production cost!


If money isn't much of a concern (as in F1) I would have thought a chemical like 2,5-Dimethylfuran could be substituted. 2,5-DMF can be derived from plant fructose and cracked in processed very similar to petrochemicals, but with potentially very low carbon impact.  The energy density of 2,5-DMF is almost equal to petrol so could fuel an F1 car with minimum additives.

With no reliance on biological processes, unlike ethanol or n-butanol (another good contender for F1 fuel), 2,5-DMF can be easily scaled up without the worries of process infection.
Title: Re: Could we make better fuels for Formula 1?
Post by: Bored chemist on 29/09/2009 18:26:57
F1 would be much more efficient and green if they filled the fuel tanks with water.
Admitedly the cars wouldn't go anywhere but driving round in circles very fast just to get back to the starting line is so far from green that the idea of "green F1" is implausible.
Title: Re: Could we make better fuels for Formula 1?
Post by: lightarrow on 29/09/2009 18:55:44
I was watching the Singapore Grand Prix yesterday, and suddenly this thought came into my mind : What if we can provide some better fuels than they use there? I was looking towards Hydrogen, but then it occurred to me that it does not provide enough power per litre.

Can anyone tell me of the fuels that can be less polluting, and yet more efficient than petrol?
An example is methyl alcohol. It has an higher power for unit volume of air/fuel mix (at stoichiometric concentration, of course); furthermore it cools more the mix when vaporizes so the mix is denser and you can go to higher revs for the increased cooling; furthermore, the octane number of CH3OH is higher than that of gas and so you can use higher compression ratios (and increase the thermodynamic efficience)
http://en.wikipedia.org/wiki/Octane_rating

The problem is that the consumption is more than doubled with CH3OH. Without changing compression ratio and ignition time, but only the amount of fuel, I experimented, among others, methyl alcohol in my byke when I was (much) younger. Speedway bykes use that fuel too.
http://en.wikipedia.org/wiki/Motorcycle_speedway
and race cars at Indianapolis, before 2006, used pure methanol as fuel.
Ethyl alcohol is good too but is less efficient.
Title: Re: Could we make better fuels for Formula 1?
Post by: Geezer on 29/09/2009 23:45:21
It's slightly ironic that Indy 500 cars used to run on methyl alcohol, which is, arguably, a lot "greener" (I really hate that term!) than gasoline because you can produce it from all kinds of junk. If I remember correctly, methyl alcohol is a wee bit corrosive in some circumstances, but the problems are not too difficult to overcome.

Methyl alcohol could be a very good substitute for gasoline if it is synthesized from a non-fossil energy source. We would need larger fuel tanks on our vehicles, but that seems like a small price to pay if it stops the increase of CO2 in the atmosphere.
Title: Re: Could we make better fuels for Formula 1?
Post by: peppercorn on 30/09/2009 12:47:51
Methyl alcohol could be a very good substitute for gasoline if it is synthesized from a non-fossil energy source. We would need larger fuel tanks on our vehicles, but that seems like a small price to pay if it stops the increase of CO2 in the atmosphere.

Here's a table showing the energy densities of some fuels:

==== Fuel type =====   ============ Energy density ===========
                                    By Mass (MJ/kg)        By Volume (MJ/L)
Gasoline                            46.4                   34.2       
Kerosene                           42.8                   33       
Vegetable oil                      42.20                  33       
DMF (2,5-dimethylfuran)       42                     37.8       
Butanol                             36.6                   29.2       
Ethanol                             30                     24       
Methanol                            19.7                   15.6       

On the bases of weight & space of the fuel tank alone, I can't see why any race car/bike would get an advantage from running on Methanol (methyl alcohol).

Plain old veg oil looks good on these figures, but (like Diesel) the flame rate is too slow for high-revving race engines.
Title: Re: Could we make better fuels for Formula 1?
Post by: lightarrow on 30/09/2009 21:06:10
Methyl alcohol could be a very good substitute for gasoline if it is synthesized from a non-fossil energy source. We would need larger fuel tanks on our vehicles, but that seems like a small price to pay if it stops the increase of CO2 in the atmosphere.

Here's a table showing the energy densities of some fuels:

==== Fuel type =====   ============ Energy density ===========
                                    By Mass (MJ/kg)        By Volume (MJ/L)
Gasoline                            46.4                   34.2       
Kerosene                           42.8                   33       
Vegetable oil                      42.20                  33       
DMF (2,5-dimethylfuran)       42                     37.8       
Butanol                             36.6                   29.2       
Ethanol                             30                     24       
Methanol                            19.7                   15.6       

On the bases of weight & space of the fuel tank alone, I can't see why any race car/bike would get an advantage from running on Methanol (methyl alcohol).

Plain old veg oil looks good on these figures, but (like Diesel) the flame rate is too slow for high-revving race engines.
It's for this reason that I specified "It has an higher power for unit volume of air/fuel mix". In an internal combustion engine is not so important the energy per unit mass or unit volume of the liquid fuel, like in your table; what counts is the energy per unit volume of air/fuel mix. In italian is called "tonalità termica", I haven't found the translation into english.

At stoichiometric concentration, the methanol mass inside the cylinder is more than double the mass of gasoline because an equal volume of oxygen requires much more mass of methanol for a complete cobustion, so the energy released is more than double the amount written in your table. The result is that the energy released in every cycle is greater for methanol:

Fuel             energy per unit volume of fuel/air mix (KJ/litre)

gasoline     ................      3.73
ethanol      ................      3.85
methanol   ................      3.90
Title: Re: Could we make better fuels for Formula 1?
Post by: Geezer on 30/09/2009 21:19:29
Ah ha!

See, I knew it all along Peppercorn. You're full of it. Figure that out!  [;D]
Title: Re: Could we make better fuels for Formula 1?
Post by: peppercorn on 01/10/2009 11:42:41
It's for this reason that I specified "It has an higher power for unit volume of air/fuel mix".
...the methanol mass inside the cylinder is more than double the mass of gasoline...

Yes, I agree. You'll notice that I was focusing on fuel storage as an issue, not power delivered.  I am not trying to discredit the use of methanol in racing - it clearly has some major benefits as you've suggested.

On the bases of weight & space of the fuel tank alone, I can't see why any race car/bike would get an advantage from running on Methanol (methyl alcohol).

As I implied, my 'gut feeling' was that such a reduction in energy density would 'cost' too much in terms of added weight of overall vehicle, the larger aerodynamic drag and the need to refuel more often.  Considering we started talking about F1 & refuelling is now a major strategic area this is a good possible reason why we'll never see methanol fuelled F1 cars.

Looking at the closeness of the energy per unit volume of fuel/air mix you've given, I suspect the real reason methanol is preferred has more to do with its high octane rating - allowing engines to run at very high boost.

Title: Re: Could we make better fuels for Formula 1?
Post by: peppercorn on 01/10/2009 11:46:30
See, I knew it all along Peppercorn. You're full of it. Figure that out!  [;D]
Your right! I'm certainly full of something!! Can't mention what it is on TNS forum though!!!   [:I]
Title: Re: Could we make better fuels for Formula 1?
Post by: Madidus_Scientia on 01/10/2009 13:03:05
Why do jets run on kerosene? Is it because of its "tonalità termica"?
Title: Re: Could we make better fuels for Formula 1?
Post by: lightarrow on 01/10/2009 13:28:59
As I implied, my 'gut feeling' was that such a reduction in energy density would 'cost' too much in terms of added weight of overall vehicle, the larger aerodynamic drag and the need to refuel more often. 
If you refill more often you don't need a bigger tank [:)].

Quote
Considering we started talking about F1 & refuelling is now a major strategic area this is a good possible reason why we'll never see methanol fuelled F1 cars.
Probably a greater problem than that is the fact that when methanol burns, the flame is almost invisible, and this is a danger at the boxes.

Quote
Looking at the closeness of the energy per unit volume of fuel/air mix you've given, I suspect the real reason methanol is preferred has more to do with its high octane rating - allowing engines to run at very high boost.
No, it's not the only one, the others I mentiond are important too: greater energy for unit volume of the mix and so greater power for every cycle only for this reason; greater density of the mix because of the greater cooling (methanol has an higher vaporization enthalpy) and greater cooling of the engine for the same reason (which allows higher revs or greater turbo pressures).
Title: Re: Could we make better fuels for Formula 1?
Post by: peppercorn on 01/10/2009 14:30:55
If you refill more often you don't need a bigger tank [:)].
Smart-arse!!!      [;D]

It's slightly ironic that Indy 500 cars used to run on methyl alcohol, which is, arguably, a lot "greener".
Assuming Indy 500 cars no longer run on methanol, why did they stop & what do they run on now?


If Butanol or DMF were readily available (from renewable sources) would they make good F1 fuels?
Title: Could we make better fuels for Formula 1?
Post by: lightarrow on 02/10/2009 15:40:45
It's slightly ironic that Indy 500 cars used to run on methyl alcohol, which is, arguably, a lot "greener".
Assuming Indy 500 cars no longer run on methanol, why did they stop & what do they run on now?
They use ethanol now. Don't know why they stopped.
Title: Could we make better fuels for Formula 1?
Post by: lightarrow on 02/10/2009 15:42:30
Why do jets run on kerosene? Is it because of its "tonalità termica"?
Jets uses kerosene _essentially_ because they need a fuel which doesn't freeze at very low temperatures.
Title: Could we make better fuels for Formula 1?
Post by: Madidus_Scientia on 06/10/2009 09:05:32
Ah, I see.
Title: Could we make better fuels for Formula 1?
Post by: Geezer on 07/10/2009 06:48:17
Why do jets run on kerosene? Is it because of its "tonalità termica"?
Jets uses kerosene _essentially_ because they need a fuel which doesn't freeze at very low temperatures.

Why not gasoline? It's got a low freezing point too.
Title: Could we make better fuels for Formula 1?
Post by: lightarrow on 07/10/2009 11:25:36
http://en.wikipedia.org/wiki/Jet_fuel
Title: Could we make better fuels for Formula 1?
Post by: Geezer on 08/10/2009 00:01:32
Quote from above link:

"The first jet fuels were based on kerosene or a gasoline-kerosene mix, and most jet fuels are still kerosene-based."
Title: Could we make better fuels for Formula 1?
Post by: lightarrow on 09/10/2009 10:22:36
Quote from above link:

"The first jet fuels were based on kerosene or a gasoline-kerosene mix, and most jet fuels are still kerosene-based."
Which is not gasoline only...
Anyway, if you have another theory, you can express it.

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