The Naked Scientists
  • Login
  • Register
  • Podcasts
      • The Naked Scientists
      • eLife
      • Naked Genetics
      • Naked Astronomy
      • In short
      • Naked Neuroscience
      • Ask! The Naked Scientists
      • Question of the Week
      • Archive
      • Video
      • SUBSCRIBE to our Podcasts
  • Articles
      • Science News
      • Features
      • Interviews
      • Answers to Science Questions
  • Get Naked
      • Donate
      • Do an Experiment
      • Science Forum
      • Ask a Question
  • About
      • Meet the team
      • Our Sponsors
      • Site Map
      • Contact us

User menu

  • Login
  • Register
  • Home
  • Help
  • Search
  • Tags
  • Member Map
  • Recent Topics
  • Login
  • Register
  1. Naked Science Forum
  2. Profile of alancalverd
  3. Show Posts
  4. Messages
  • Profile Info
    • Summary
    • Show Stats
    • Show Posts
      • Messages
      • Topics
      • Attachments
      • Thanked Posts
      • Posts Thanked By User
    • Show User Topics
      • User Created
      • User Participated In

Show Posts

This section allows you to view all posts made by this member. Note that you can only see posts made in areas you currently have access to.

  • Messages
  • Topics
  • Attachments
  • Thanked Posts
  • Posts Thanked By User

Messages - alancalverd

Pages: [1] 2 3 ... 713
1
Chemistry / Re: How can I find the optimum ΔH and ΔS for passive T control?
« on: Today at 10:54:42 »
But you can start with a tank of liquid and a fairly small head space. LV decreases with increasing pressure but may remain practicable up to 1000 bar or so depending on the critical point of the liquid.

Or consider a sublimating solid?

2
Just Chat! / Re: a suitable pseudonym
« on: Today at 07:12:26 »
Drifting off topic as usual, but should we drive Porsches on autobahns? Or Volkswagens at all?

Should you eat any vegetable that owes its bulk to the Haber process?

Should all the decent, intelligent US presidents refund their Rhodes scholarships?

3
Chemistry / Re: How can I find the optimum ΔH and ΔS for passive T control?
« on: Today at 06:56:43 »
The idea is not entirely impractical.

As BC says, it does depend on having really good insulation but if you know your maximum insolation, minimum outdoor temperature, conductivity of your exterior cladding, and internal heat load (say 100W per person plus whatever other stuff you have in the building) you can calculate the mass of phase-change material required to keep the interior wall close to the melting point provided the night temperature is below your target for long enough.

And a practical thought: whilst heat storage systems have been proposed and implemented around melting, it's worth noting that the latent heat of vaporisation of water is about 7 times that of fusion, and the transition temperature can be relatively easily controlled by changing the pressure in the containment vessel. Worth looking at some more volatile materials?   

4
Physics, Astronomy & Cosmology / Re: Is there a net heat exchange between water and ice at 0 degree C?
« on: Today at 06:38:16 »
Quote from: hamdani yusuf on Today at 04:51:06
Quote
from: alancalverd on Yesterday at 20:31:28
Heat (i.e.thermal energy) can only flow from a higher to a lower temperature.
That's true by definition.

So you agree that if ice and water are in contact at 0°C, no net heat will flow between them?

5
New Theories / Re: what is temperature?
« on: Yesterday at 23:22:50 »
Quote from: Spring Theory on Yesterday at 20:09:02
My point was that Entropy is the log of something.  The log of something has no units.

S = -kBlogp where kB, Boltzmann's constant, has dimensions ML2T-2K-1, so S is far from dimensionless.

6
New Theories / Re: what is temperature?
« on: Yesterday at 23:13:57 »
Quote from: Bored chemist on Yesterday at 09:05:40
No, it was the release of Wigner potential energy that raised the temperature. Problem is that once you reach the annealing temperature you can initiate a chain reaction that outstrips the cooling capacity of the system - as happened at Windscale.
So, what happened was the transfer from one particular degree of freedom to all the others.
It's an odd use of "degree of freedom".  Wigner energy is potential energy stored as microscopic areas of mechanical stress when a neutron displaces an atom from its lattice position into a metastable trap. Wigner release is the conversion of that potential energy into phonons (i.e. heat) as the atom returns to a stable position. It's the "whole atom" equivalent of thermoluminescent electron trapping resulting from gamma radiation.   

7
Physics, Astronomy & Cosmology / Re: Is there a net heat exchange between water and ice at 0 degree C?
« on: Yesterday at 20:31:28 »
Heat (i.e.thermal energy) can only flow from a higher to a lower temperature. Therefore there will be no net exchange through the barrier if the water and ice are at the same temperature.

If you can make water flow uphill, or indeed put the sh1t back in the donkey by any means, you are doing better than God.

8
New Theories / Re: An essay in futility, too long to read :)
« on: Yesterday at 17:36:22 »
Quote from: yor_on on Yesterday at 11:51:59
And I'm ashamed of my species.

We agree on this.

9
Just Chat! / Re: Why are cigarette smokers so brand loyal?
« on: Yesterday at 16:23:27 »
All smokers have a common death wish, but express their personalities differently.

I see that menthol cigs, the outward sign of a bizarre sexual preference,  are now banned in the UK.
Practically all the other brands taste pretty much the same and label the user as an antisocial moron, but
Quote
In July 2016, the French government considered a ban on both the Gitanes and Gauloises cigarette brands because they were deemed "too stylish and cool".
which is why I smoked them in my cool, stylish youth. But since the UK  government has banned smoking in indoor public spaces, I have to rely on aviator shades and a 32-bar bass solo to pull the chicks. 

10
New Theories / Re: what is temperature?
« on: 24/05/2022 21:16:39 »
Quote from: Bored chemist on 24/05/2022 13:56:17
"The potential energy of a strained lattice may be enormous"
yes, it was the cause of the Windscale fire- it made the graphite very hot...
No, it was the release of Wigner potential energy that raised the temperature. Problem is that once you reach the annealing temperature you can initiate a chain reaction that outstrips the cooling capacity of the system - as happened at Windscale.

11
Just Chat! / Re: Why are cigarette smokers so brand loyal?
« on: 24/05/2022 21:10:35 »
A habit is a habit, and becomes part of a personality and identity. Ask any addict or churchgoer.

12
Physics, Astronomy & Cosmology / Re: How can I pass a large DC current through mercury?
« on: 24/05/2022 21:08:18 »
Quote from: Bored chemist on 24/05/2022 16:42:06
Quote from: alancalverd on 23/05/2022 18:28:25
The reason mercury was so useful in barometers stems from its low vapor pressure at room temperature
And there was me thinking it was the density..
Presumably all the ten metre high barometers full of water  somehow escaped my attention.
The water vapour pressure is a complication, but you could allow for it.
If you had a liquid of similar density but high vapor pressure, the barometer would be more sensitive to temperature. Not a problem for a laboratory instrument where you can apply any number of corrections but an additional complication at sea. 

13
General Science / Re: How do we make synthetic gasoline?
« on: 24/05/2022 21:04:39 »
Thanks in part to Margaret Thatcher, whose most significant political acts were to welcome General Pinochet to the UK, install gates across Downing Street, and assume the role of Head of State previously held by the Queen, one third of THE ECONOMY  is spent on mortgages.

If wind power isn't free, why are people so excited by it?

14
New Theories / Re: what is temperature?
« on: 24/05/2022 12:36:42 »
Quote from: Spring Theory on 24/05/2022 12:15:19
This is why temperature is in units of energy.
No. The mean energy of a particle within a body is kBT  where kB is the Boltzmann constant, whose dimensions are joules per kelvin.

Quote from: Spring Theory on 24/05/2022 12:15:19
Entropy is dimensionless.
No. The dimensions of entropy are joules per kelvin.

15
General Science / Re: How do we make synthetic gasoline?
« on: 24/05/2022 12:26:38 »
As long as the input energy is free, that isn't a problem. It's a possible solution to  transport problems: you can use free wind power to make a fuel compatible with all existing vehicles including ships and planes, with no net carbon emission.

16
New Theories / Re: what is temperature?
« on: 24/05/2022 10:23:02 »
Quote from: Bored chemist on 24/05/2022 09:00:37
Quote from: alancalverd on 23/05/2022 18:41:38
Quote from: Spring Theory on 23/05/2022 14:10:06
Temperature is the amount of energy required to change the entropy by one bit.
So the entropy of an object at constant temperature is continually changing?  Welcome to the world of Hamdani Yusuf!
The gradient is d height/ d distance .
That doesn't mean that all hills are moving.
That's not H Y's world, nor S T's world.
It's only in your world.
So if T>0, by ST's statement there is plenty of available energy in the system to change its entropy, and nothing to stop it.

17
New Theories / Re: what is temperature?
« on: 24/05/2022 10:20:34 »
Quote from: Bored chemist on 24/05/2022 08:57:08
It's any form of energy.
Er, no. The potential energy of a strained lattice may be enormous, but as that can't be transferred by thermal conduction to another body, it doesn't affect its temperature.

There's a discussion elsewhere about dissolving a stressed spring.

18
Physics, Astronomy & Cosmology / Re: How can I pass a large DC current through mercury?
« on: 24/05/2022 10:15:33 »
Just as well the US Navy (nor Roscosmos, in the early days) don't watch Youtube.

science.howstuffworks.com/rail-gun1.htm

19
Physics, Astronomy & Cosmology / Re: Is there a net heat exchange between water and ice at 0 degree C?
« on: 24/05/2022 10:10:59 »
Quote from: hamdani yusuf on 24/05/2022 03:45:40
It only shows that average temperature of an object (ice-water mixture) can be different than local temperature at specific location
An average being different from a sample? My god, he's invented statistics! There's a Nobel physics prize awaiting if you can demonstrate it, and  Fields Medal if you can present a mathematical proof. Or maybe not.

20
General Science / Re: How do we make synthetic gasoline?
« on: 24/05/2022 10:08:42 »
Audi have made synthetic gasoline directly from atmospheric CO2 and H2O. Almost as efficiently as a tree.

Pages: [1] 2 3 ... 713
  • SMF 2.0.15 | SMF © 2017, Simple Machines
    Privacy Policy
    SMFAds for Free Forums
  • Naked Science Forum ©

Page created in 0.088 seconds with 64 queries.

  • Podcasts
  • Articles
  • Get Naked
  • About
  • Contact us
  • Advertise
  • Privacy Policy
  • Subscribe to newsletter
  • We love feedback

Follow us

cambridge_logo_footer.png

©The Naked Scientists® 2000–2017 | The Naked Scientists® and Naked Science® are registered trademarks created by Dr Chris Smith. Information presented on this website is the opinion of the individual contributors and does not reflect the general views of the administrators, editors, moderators, sponsors, Cambridge University or the public at large.