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First off, thanks so much for replying to an old post. I think we're not on the same page yet.That was methylamine. I understand the ionic part.I have ethyl methylamine, a secondary amine. If it works out the same as your suggestion the positive charge is on the Hydrogen, but it's in the middle of the structure.I'm thinking this: CH3CH2NHCH3 + HBr → CH3CH2NH2+CH3 Br-Anyway, thanks again.mvw