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I am not sure what you are suggesting, technind, but you cannot produce a metemeric match outside the gamut of the three primaries of the display.
The analysis curves of the eye are not 'red, green and blue'. They are all very broad and include sensitivity to many wavelengths.
The spectra of the primariy phosphors in displays are not broadband but optimised for colourimetry and brightness (and cost, no doubt).
What you can do from a tri-primary display is create a colour which is a slightly desaturated version of a colour which is out-of-gamut