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Mold or mould is correct - the former is more commonly used
There are yet another group of poisons produced by bacteria. Probably the best known is botulinum toxin. Ironically this is well known due to its use as botox in spite of being one of the most poisonous materials known.Some of these chemicals are destroyed by heating, but not all of them, so yes, it is possible to get food poisoning from food that has been well cooked. Botulinum toxin is destroyed by heating, but others are not.