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The gunge that is widely used on television is an industrial powder thickener called Natrosol.
What are your goals?
Slimy is good. Some of the thickeners that go into jams and pie fillings might work well. If you include some edible chunks of marshmallow, or diced fruit, you can emphasize the grossness by sticking your hand into it and shoving some of it into your mouth.
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No, but the DIY store might.Some wallpaper pastes are based on the same stuff.Add some food dye and you are well on the way.The problem with stinky things is that they are often toxic. You can try onions.
I think that there's often fungicides in wallpaper paste, you'd have to be a bit careful.
How about rotten unboiled eggs! They're pretty gooey, non toxic and smell disgusting!you could maybe even get them for free at some places?