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Wiki says: "only a small minority of elements are found as recognizable, relative pure minerals. Among the more common of such "native elements" are copper, silver, gold, carbon (as coal, graphite, or diamonds), sulfur, and mercury. All but a few of the most inert elements, such as noble gases and noble metals, are usually found on Earth in chemically combined form, as chemical compounds. While about 32 of the chemical elements occur on Earth in native uncombined form, most of these occur as mixtures. For example, atmospheric air is primarily a mixture of nitrogen, oxygen, and argon, and native solid elements occur in alloys, such as that of iron and nickel."http://en.wikipedia.org/wiki/Chemical_element