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Urine is quite a good fertiliser but there is a chance that it is a bit strong for most plants so it is best diluted before putting onto plants directly. Where it will do most good however is on a compost heap where it will help the plant material decay more quickly. So you should pee on your compost heap and dilute it for your plants.
Some years back, a friend and I had a competition to grow the tallest sunflower. Him being a heavy drinker, "Watered" his with his urine after his nightly visits to the local pub.I used plain old tap water.His outgrew mine by quite a lot, does this mean anything? Possibly not.