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19th Jun 2011
Coal Gasification and Carbon Capture
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This week, we find out how to get useful gas from useless coal, and make money from waste carbon dioxide! Underground coal gasification could allow us to access huge amounts of energy in inaccessible coal seams. We find out how it works as well as exploring a new method for capturing waste carbon and turning it into useful chemicals. In the news, dinosaurs inspire new designs for aircraft, spotting a star being ripped apart by a black hole, and the South African bid for the world's biggest radio telescope. Plus, Diana asks what the point is of "junk" DNA?
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News
An unique astronomical event – an incredibly bright and long lived burst of gamma rays – was probably the result of a black hole destroying a star, according to research published in the journal Science this week.
Comet Hartley 2 has been found to be a more varied place than was previously expected
Porous molecules, useful in a huge range of applications including separating chemicals and catalysing reactions, may be designed on demand thanks to a new method published in the journal Nature this week.
By learning from pterosaurs we may be able to make aircrafts more manouverable.
Questions

Why are synfuels cleaner than traditional fuels?
Dermot - They're cleaner because your starting point is essentially pure hydrogen and carbon monoxide, so you've got no sulphur in there. As long as you're blowing your gasification with oxygen rather than air you've got no nitrogen in there to give you oxides of nitrogen, so you really ought to be able to synthesise a designer fuel, which is effectively what you do. It can be a diesel type fuel, a petrol type fuel, an equivalent of jet kerosene for aircrafts... Ultimately the car companies would like to make an engine that's a combination of a spark ignition engine and a compression ignition engine. They'll specify exactly what properties they want the fuel to have and we can make that.
Ben - So by spark ignition you mean - petrol engines are spark ignition, but the compression...
Dermot - Yes, diesel engines are compression engines and they would like to get away from that situation. We have to make two types of engine for two types of vehicle and just make one fuel that has the advantages of both. They'll specify exactly how they want that fuel to perform and we synthesise that.

Can we make recycled oil from carbon dioxide?
Joe - Well, taking CO2 and reconverting it into fuel, CO2 itself is completely spent fuel so one has to add energy to go back up the thermodynamic curve from carbon dioxide to usable fuel. The most efficient chemistry for doing so is photosynthesis. It is an intricate process that adds energy from sunlight. Nothing else that man has done on a pathway has approached the efficiency of photosynthesis. At Skyonic, we’ve been working with the University of Texas on bio-algal fuels made from bio-algae. We’ve been feeding it with bicarbonate of soda manufactured from our SkyMine process and they've reported very good results. 90% incorporation of the CO2 and a tripling of the growth rate because it actually creates an algae bloom. It also throws some of the biologic triggers inside the algae that make it produce oil preponderantly compared to plant matter.
Ben - So we can't mimic nature yet, but we can of course get nature to do that work for us.
Joe - We can hitch a ride on nature at this point and it’s probably the most promising means for making fuel directly from CO2.

How can coal be converted to petrol?
Dermot - Well the South Africans have been doing this for a very long time because of the years of sanctions. The well-known technology is called Fisher-Tropsch technology and that can be used to synthesise hydrocarbon chains. Traditionally, the process was used for synthesising diesel but you can synthesise a naptha-type material if you want to or a kerosene type material. It’s just a question of optimising the reaction conditions and choosing the right catalyst. People are starting to develop a range of fuels now from synthesis gas.

What are the harmful impacts of underground coal gassification?
Dermot - It’s very important to do it at depths where all of the water has been formally classified as permanently unusable. These are very, very salty water deposits at depths of a kilometre or thereabouts. Nobody would ever extract those kind of waters, the very fact that they are heavily salty means they're poisonous anyway. You have to be operating at the kind of depths where nobody would ever bring that water to the surface as a water supply. Then no matter what happens, you're not going to cause contamination that causes any problems.

Can coal power plants use catalytic converter technology?
Joe - Well, catalysts generally don't change chemistry. They only drive it at accelerated speeds to the same end. When a power plant operates perfectly it does achieve complete combustion. So, a catalytic converter may be good for making carbon monoxide into truly carbon dioxide. It’s still carbon dioxide at the end of it so you can't clean up with that fashion. You can only change it from a gaseous form into a mineralised form or into some other form. You have to change state.
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Interviews
The Square Kilometre Array, or SKA, should help us to answer some of the big outstanding questions about our universe. It will either be located in Australia or South Africa. Bernie Fanaroff, project manager for the South African SKA bid, met up with Chris Smith…
Radiocarbon dating is an extremely accurate and useful tool to date archaeological finds which contain any previously living material.
Underground coal gasification is a way to get useful fuel from otherwise inaccessible coal seams that are simply un-economical to mine.
Skyonic have developed “Skymine”, a system that not only extracts CO2 but actually turns it into something they can sell!
This week we are in Cambridge’s Museum of Technology to explore the engineering of an iconic bit of coal-fired power – the steam engine...
QotW
We explore the purpose of junk DNA...
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