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Chemistry / Is this a valid model of electron architecture in different elements?
« on: 01/06/2004 16:04:00 »
Tools of construction of system of elements.
www.genevo.org/B.htm
An old model of atom does not answer many questions about properties. And... I decided to offer you a new one. It is called "ball-bearing model of atom". It is very flexible and it can be twisted!
www.genevo.org/F.htm
Mechanisms of cyclicity in atom
It is logical, that shown cyclicity for d-elements is shown also in other families.
http://www.genevo.org/Z1.htm
I have tried to simplify last model maximum.
Secondary periodicity see at figure (the schedule of the data).
www.genevo.org/S.htm
In my last work I show secondary periodicity on this property for s-elements on the example of the data on electron affinity. In the same place, on the example of d-elements other logic of the tableis visible, - not periodicity but cyclicity.
Some properties are cyclic and not correspond to the periodic table.
I offer to your attention http://www.genevo.org/H.htm
It is visible on the schedule that on the property of electron affinity s-elements behave variously before p and d-elements . Before ð - elements electron affinity grows, before d-falls.
Even on this property it is possible to speak about available laws which are not clear yet.
The secondary periodicity
Secondary periodicity is connected with repeated filling of everyone
orbital by the second electron and with relative positioning of orbitals.
Secondary periodicity is more brightly expressed at last families.
Similarity by orbital structure can be various.
Orbitals may be focused in one direction, thus,
electronic configurations of compared atoms may not coincide.
update www.genevo.org./E.htm
bout the same scheme of cyclicity it is possible to make for all other families.
Except of cyclicity of orbitals 3 2 3 2 for d-elements, there exist such cyclicities – “reversed”, "regressive" and "progressive". For their construction it is necessary to number orbitals.
But also other cyclicity exists which is connected with growth of number of electrons in atom. When electron is filling , the cyclicity is defined by occurrence of every new electron instead of orbital for two electrons.
Different types of cyclicity connected with representing of different properties of atom http://www.genevo.org/E.htm
The continuation of the table of overjumpings of electrons http://www.genevo.org/OD.gif - the table of electrochemical series (fragment). http://www.genevo.org/E.htm
In this periodic table an electrochemical series of potentials of 3d-elements and 5d-elements is very similar. It is shown on the graph. http://www.genevo.org/Ef2.gif And a series of electrochemical potentials of 4d-elements is differing from series of potentials of 3d-elements and 5d-elements. If to turn this series and increase on-1 you see that areas of maxima and minima of this series will coincide with the areas of maxima and minima of electrochemical series of potentials of 3d-elements and 5d-elements. Graph http://www.genevo.org/Ef2.gif
During orbital’s filling with electrons, power areas form inside atom - with superfluous quantity of electrons and insufficient quantity. It causes overjumpings of electrons. My theory about such overjumpings see on www.genevo.org. I nead your comments
www.genevo.org/B.htm
An old model of atom does not answer many questions about properties. And... I decided to offer you a new one. It is called "ball-bearing model of atom". It is very flexible and it can be twisted!
www.genevo.org/F.htm
Mechanisms of cyclicity in atom
It is logical, that shown cyclicity for d-elements is shown also in other families.
http://www.genevo.org/Z1.htm
I have tried to simplify last model maximum.
Secondary periodicity see at figure (the schedule of the data).
www.genevo.org/S.htm
In my last work I show secondary periodicity on this property for s-elements on the example of the data on electron affinity. In the same place, on the example of d-elements other logic of the tableis visible, - not periodicity but cyclicity.
Some properties are cyclic and not correspond to the periodic table.
I offer to your attention http://www.genevo.org/H.htm
It is visible on the schedule that on the property of electron affinity s-elements behave variously before p and d-elements . Before ð - elements electron affinity grows, before d-falls.
Even on this property it is possible to speak about available laws which are not clear yet.
The secondary periodicity
Secondary periodicity is connected with repeated filling of everyone
orbital by the second electron and with relative positioning of orbitals.
Secondary periodicity is more brightly expressed at last families.
Similarity by orbital structure can be various.
Orbitals may be focused in one direction, thus,
electronic configurations of compared atoms may not coincide.
update www.genevo.org./E.htm
bout the same scheme of cyclicity it is possible to make for all other families.
Except of cyclicity of orbitals 3 2 3 2 for d-elements, there exist such cyclicities – “reversed”, "regressive" and "progressive". For their construction it is necessary to number orbitals.
But also other cyclicity exists which is connected with growth of number of electrons in atom. When electron is filling , the cyclicity is defined by occurrence of every new electron instead of orbital for two electrons.
Different types of cyclicity connected with representing of different properties of atom http://www.genevo.org/E.htm
The continuation of the table of overjumpings of electrons http://www.genevo.org/OD.gif - the table of electrochemical series (fragment). http://www.genevo.org/E.htm
In this periodic table an electrochemical series of potentials of 3d-elements and 5d-elements is very similar. It is shown on the graph. http://www.genevo.org/Ef2.gif And a series of electrochemical potentials of 4d-elements is differing from series of potentials of 3d-elements and 5d-elements. If to turn this series and increase on-1 you see that areas of maxima and minima of this series will coincide with the areas of maxima and minima of electrochemical series of potentials of 3d-elements and 5d-elements. Graph http://www.genevo.org/Ef2.gif
During orbital’s filling with electrons, power areas form inside atom - with superfluous quantity of electrons and insufficient quantity. It causes overjumpings of electrons. My theory about such overjumpings see on www.genevo.org. I nead your comments