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  4. Would a pipe made of synthetic diamond erode and be corroded with seawater?
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Would a pipe made of synthetic diamond erode and be corroded with seawater?

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Offline remotemass (OP)

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Would a pipe made of synthetic diamond erode and be corroded with seawater?
« on: 24/11/2022 18:42:02 »
Seawater erodes all sorts of materials including metals but would a pipe of diamond survive for a long-time in the ocean in permanent contact with the seawater?

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Offline Bored chemist

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Re: Would a pipe made of synthetic diamond erode and be corroded with seawater?
« Reply #1 on: 24/11/2022 19:39:20 »
Probably pretty much forever.
Certainly long enough to get covered in barnacles.
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Offline evan_au

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Re: Would a pipe made of synthetic diamond erode and be corroded with seawater?
« Reply #2 on: 24/11/2022 20:03:58 »
Metals degrade because they get oxidised by dissolved oxygen, and the water acts acts an electrolyte - and it happens much faster if there is an electrical connection to another metal. So ships and undersea pipelines have a "sacrificial anode" (eg zinc) that gets eroded instead the steel pipe. But if the sacrificial anode is not replaced before it is eroded, the steel will start to corrode.
That's assuming someone doesn't put a demolition charge on the pipeline, as appears to have happened recently in the Baltic Sea...
https://en.wikipedia.org/wiki/Galvanic_anode

Diamond is very strong due to its interlinked tetrahedral crystal structure. But at the surface are "loose" carbon bonds, which are much more reactive. Dissolved oxygen will react with these bonds, exposing yet more unpaired carbon bonds, and slowly eroding the diamond.
- These loose bonds will also react with hydrogen, producing a self-terminating chemical reaction (a hydrocarbon surface)
- But jewellers often clean diamonds with hydrofluoric acid, which will react with the loose bonds, producing a very non-reactive fluorocarbon surface.
- Another option is if the tetrahedral diamond carbon structure could coated with something like a graphene carbon surface, which has no loose bonds? But mechanically, it would be fairly weak compared to the underlying diamond structure...
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Offline Bored chemist

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Re: Would a pipe made of synthetic diamond erode and be corroded with seawater?
« Reply #3 on: 24/11/2022 23:24:36 »
Quote from: evan_au on 24/11/2022 20:03:58
if the tetrahedral diamond carbon structure could coated with something like a graphene carbon surface,
The graphene would act as kindling.
https://en.wikipedia.org/wiki/Graphene#Chemical
Quote from: evan_au on 24/11/2022 20:03:58
graphene carbon surface, which has no loose bonds
Graphene is entirely covered with loose bonds and is rather reactive.
Quote from: evan_au on 24/11/2022 20:03:58
But at the surface are "loose" carbon bonds, which are much more reactive. Dissolved oxygen will react with these bonds, exposing yet more unpaired carbon bonds, and slowly eroding the diamond.
If that was significant, the same process would occur in the absence of water  and indeed, it does. Diamonds will burn in air.
But the reaction is so slow that you need to work on it.

Adding water will slow down the oxidation.

Diamonds in seawater are pretty much "forever".
The sun will boil the oceans before the diamonds dissolve (unless you make them impractically thin).


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