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That does sound gross and I have never heard of such a practice. The urine of many unneutered mammals( male ) does frequently have a strong odour. The "boss"(Alancalverd vernacular) and myself run a small scale cat shelter-tom cat pee is the bane of my life!
I suspect a lot of the answer is "because they can". Goats are curious, intelligent and competitive animals who will explore anything and everything. Unneutered males? Think teenage boys, with four legs.