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The skin depth at 50Hz is quite a lot, actually, for the low resistivity metals - several cm before the current is 1/2 value. They often use multiple strands on big current conductors, and I think that is part of the reason.The effective AC resistance (and power factor considerations, of course) makes it better to transmit over long distances (point to point) using DC.It is at RF that it becomes really significant.
What I have heard they do sometimes do with big conductors carrying AC is to have an inner core of high strength steel which may not be an ideal resistance, and have a lower resistance metal on the outside which may not carry much mechanical strength.to the actual resistance of the wire.