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Bismuth, which has been known since ancient times, was often confused with lead and tin. Bismuth was first shown to be a distinct element in 1753 by Claude Geoffroy the Younger. Bismuth does occur free in nature and in such minerals as bismuthinite (Bi2S3) and bismite (Bi2O3). The largest deposits of bismuth are found in Bolivia, although bismuth is usually obtained as a by-product of mining and refining lead, copper, tin, silver and gold.Pure bismuth is a white, brittle metal with a slight pink color. Bismuth is usually mixed with other metals, such as lead, tin, iron or cadmium to form low-melting alloys. These alloys are used in such things as automatic fire sprinkler systems, fire detection systems and electrical fuses.Bismuth oxide (Bi2O3), a bismuth compound, is used as a yellow pigment in paints and cosmetics. Bismuth oxychloride (BiOCl) is used to make a pigment known as bismuth white. Bismuth carbonate (Bi2(CO3)3) is used to treat diarrhea and gastric ulcers.Once thought to be the heaviest stable isotope to exist in nature, experiments conducted in 2002 showed that bismuth-209 is unstable and decays into thallium-205 through alpha decay. Bismuth-209 has a half-life of roughly 19,000,000,000,000,000,000 years.