0 Members and 1 Guest are viewing this topic.
Quotethis glass-sheet demonstration would work in a vacuum.That, again, is merely a statement. Have you any evidence of this.You might bear in mind that the force which has been measured can be explained by atmospheric pressure.What value do these inter molecular forces have, btw? Can you quote a value from somewhere. You imply that it has been measured. It would have huge implications on things like the boiling point of water, for instance.
this glass-sheet demonstration would work in a vacuum.
The value has been measured- it's about 2.5KJ/g
The strong intermolecular forces between (polar) water molecules are why water has higher boiling point than similar sized molecules, e.g. water (H20) is liquid at room temperature, whereas ammonia (NH3) and methane (CH4) are gases at room temperature.Hydrogen cyanide (HCN) boils at 26oC.
That's fair enough. I was trying to relate it to a possible 'tensile strength' so the number would be handy. I don't think that pressure vs boiling point is irrelevant. Doesn't it relate to the energy needed to make a surface molecule break free? If there is even a hint of a surface anywhere within the liquid bulk then it can form a bubble at a low enough pressure and any tension you might have had will not count. This argument would not prohibit dynamic tension, as long as the load is applied briefly enough.But, if a normal lift pump will not operate over a greater height than that which corresponds to atmospheric pressure for the liquid density, then how can an inverted u tube support a greater head?I appreciate that, in a small bore tube, the effects of the tube surface could make a difference but, in a bulk liquid, what can keep a column above that which is supported by the AP difference?The paper quoted above agrees with my point - it doesn't work for static pressures below the saturated vapour pressure.
I wish you could tell me the difference between the top of a U tube and the top of a single tube...
I wish you could tell me the difference between the top of a U tube and the top of a single tube. Particularly if the tube had a 'domed' top. Assume that the vertical height is greater than the 10m , conventional, limit.The molecules need to stick to the top surface whether it's a U or just the top of the tube.On the attached diagram, the region in the upper section of both the single vertical and the U tube are under exactly the same conditions. How is the water supposed to stick to the top of one yet not to the other? How do the molecules 'know' that they are in different bits of apparatus so that they can behave differently? A loop of string stuck to the top of either curve would pull away from the upper surface just as easily. Whatever the tension may have been, the liquid would not 'stick' to the top any easier for either case.Can't you see my problem?
The video link about the ocean circulation was readily dismissed by yourself. That video shows clearly how a sinking denser ocean water can cause a dragging effect on water from the equator pulling up warm less dense water thousands of miles.
For anyone who doesn't know exactly 'how trees work' or has their own ideas about it, I suggest you take a look at this link. It is a Google Book review and does not show all the pages but there is plenty of evidence which you can read of a well thought out bit of Science which takes the magic out of the mechanisms used by plants to raise water.The main point about it, as far as I am concerned, is that it depends upon the Xylem tubes being extremely thin. Cavitation is always a problem and can stop the process.The mechanism does not rely on 'flow' or inverted U tubes. It is described and explained in terms which make sense and do not go against any established ideas.
I am, basically, a reductionist. If there is a theory which explains a phenomenon and it doesn't involve needlessly new complications then I tend to find it acceptable. Science, in general, looks to explain the World with a minimum of 'laws'. The book in that link manages to give explanations for the phenomena involved with tree sap movement which don't need to introduce any new 'fanciful' ideas. Actual numerical values are quoted and that always reassures me that someone knows what they are talking about. The effect of adhesion and cohesion, taken together is considered and there is a very reasoned discussion of the actual forces involved and the requirement for tubes of the sort of size that Xylem uses. No magic and nothing actually new - just an intelligent approach which uses values drawn from elsewhere in Science.
I mention cavitation because that is something which couldn't be dealt with if the cavities were large.