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  1. Naked Science Forum
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  4. Does gold react with sulphuric acid?
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Does gold react with sulphuric acid?

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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #20 on: 16/04/2009 05:44:12 »
what is the product of
H2SO4+HNO3=  ?
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #21 on: 16/04/2009 05:53:25 »
Ooo! I was just doing that yesterday! [:)]

HNO3 + H2SO4 ↔ NO2+ + HSO4- + H2O

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Offline Raghavendra

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Does gold react with sulphuric acid?
« Reply #22 on: 16/04/2009 06:17:56 »
It's a simple answer any one would have answered it....


 Answer is H2O+NO2+(-)HSO4
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Offline lightarrow

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Does gold react with sulphuric acid?
« Reply #23 on: 16/04/2009 13:02:18 »
Yes, however the acids must be quite pure (almost no water) and H2SO4 must be in excess (to bind the water molecule formed in the reaction) or the very strong acid NO2+ will react again with water:

NO2+ + H2O --> HNO3 + H+.
« Last Edit: 16/04/2009 13:05:39 by lightarrow »
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #24 on: 16/04/2009 13:08:45 »
Do you have to keep the temperature of the solution low?
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Offline lightarrow

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Does gold react with sulphuric acid?
« Reply #25 on: 16/04/2009 13:09:43 »
Quote from: Chemistry4me on 16/04/2009 13:08:45
Do you have to keep the temperature of the solution low?
Don't think so.
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #26 on: 16/04/2009 13:19:01 »
Higher temperature favors the dinitration product when adding nitro groups onto an aromatic ring right? Or is that just my memory playing games?
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Offline lightarrow

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Does gold react with sulphuric acid?
« Reply #27 on: 16/04/2009 15:15:26 »
Quote from: Chemistry4me on 16/04/2009 13:19:01
Higher temperature favors the dinitration product when adding nitro groups onto an aromatic ring right? Or is that just my memory playing games?
This is a different question.
Yes, higher T favors the nitrations but sometimes these reactions are auto-catalityc or the products can decompose in presence of the reagents, so you have to keep the T low enough if you don't want to go to hospital...
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #28 on: 17/04/2009 02:55:17 »
Okay, got that. Thanks. [:)]
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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #29 on: 17/04/2009 09:50:30 »
What happens when this solution is heated?
NO2+ + HSO4- + H2O
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #30 on: 17/04/2009 09:56:13 »
What do you want to do?
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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #31 on: 17/04/2009 10:41:11 »
I am mixing HNO3 and H2SO4 in the ration of 4:1, and heating it to drop on IC to make the die visible (for etching plastic).
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Offline lightarrow

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Does gold react with sulphuric acid?
« Reply #32 on: 17/04/2009 14:53:15 »
Quote from: Dr.IC on 17/04/2009 10:41:11
I am mixing HNO3 and H2SO4 in the ration of 4:1, and heating it to drop on IC to make the die visible (for etching plastic).
1.Why 4:1?
2.The HNO3 is more than 98%?
3.You use that mix to dissolve plastic or what, exactly?
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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #33 on: 21/04/2009 04:38:43 »
This is to etch epoxy or plastic any of this...
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #34 on: 21/04/2009 04:39:59 »
Ah, finally. The answer. And some sanity too. [:)]
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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #35 on: 21/04/2009 04:49:41 »
Quote from: lightarrow on 17/04/2009 14:53:15
Quote from: Dr.IC on 17/04/2009 10:41:11
I am mixing HNO3 and H2SO4 in the ration of 4:1, and heating it to drop on IC to make the die visible (for etching plastic).
1.Why 4:1?
2.The HNO3 is more than 98%?
3.You use that mix to dissolve plastic or what, exactly?

I dont know y v r using 4:1, and The HNO3 is 98%
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Offline Chemistry4me

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Does gold react with sulphuric acid?
« Reply #36 on: 21/04/2009 04:52:33 »
Quote from: Dr.IC on 21/04/2009 04:49:41
I dont know y v r using 4:1
Eh? Is your keyboard broken?

------

Are you trying to say: I dont know why they are using 4:1?
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Offline Dr.IC (OP)

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Does gold react with sulphuric acid?
« Reply #37 on: 21/04/2009 07:38:42 »
Quote from: Chemistry4me on 21/04/2009 04:52:33
Quote from: Dr.IC on 21/04/2009 04:49:41
I dont know y v r using 4:1
Eh? Is your keyboard broken?

------

Are you trying to say: I dont know why they are using 4:1?
i was taking about our team. our team has been trained to use the above spec.
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