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Are you technically savvy with the physics/chemistry here and can tell me that it just won't work?
Vinegar sounds great. But I think you must soak it in vinegar for some time, right? I can't just rub with vinegar and expect it to chemically alter the rust, can I?
Well, I can't soak the car in vinegar.
So maybe I need to make a paste of the vinegar, somehow, and smear that on. So how would I make a paste for this purpose? i.e. a paste that doesn't neutralize the vinegar?