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I heard that it may well be far older than this, as there is a description of a roman glass blower showing the emperor a new type of glass that was almost impossible to break. The emperor asked him whether anyone else knew the secret, he proudly said no, and then the emperor promptly killed him. This was becasue the emperor had a huge investment in glass and didn't want it to become worthless with the invention of a better type of glass...Apparently there is only one thing you can add to glass to give it this sort of property and that is boron, so it is thought that the unfortunate glassblower invented pyrex. Unforutnately the intelectual property environment in the Roman empire was not really conducive to its wider adoption...