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this is the best i/ve heard it explained.... quoted from eric hawthorn'This is a trickier question than it may seem.In quantum mechanics, there is no such thing as a persistently isolated system. Even a black hole radiates, due to quantum fluctuations across its event horizon (Hawking).So in a precise analysis, we could say that the second law, which applies only to isolated systems, is inapplicable. It would be true of isolated systems if they existed, but they don’t.However, physics these days talks about “effective” theories. These theories work within limited regimes, such as within an energy range. At the boundaries of the regime/range, that theory falls apart and no longer explains things. It’s fair to say I think that a lot of the most up to date physics consists only of these limited-applicability effective theories. I think we have to say that the second law of thermodynamics is also only such an effective theory.This is a trickier question than it may seem.In quantum mechanics, there is no such thing as a persistently isolated system. Even a black hole radiates, due to quantum fluctuations across its event horizon (Hawking).So in a precise analysis, we could say that the second law, which applies only to isolated systems, is inapplicable. It would be true of isolated systems if they existed, but they don’t.However, physics these days talks about “effective” theories. These theories work within limited regimes, such as within an energy range. At the boundaries of the regime/range, that theory falls apart and no longer explains things. It’s fair to say I think that a lot of the most up to date physics consists only of these limited-applicability effective theories. I think we have to say that the second law of thermodynamics is also only such an effective theory."
In quantum mechanics, there is no such thing as a persistently isolated system.
Even a black hole radiates, due to quantum fluctuations across its event horizon (Hawking).