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Quote from: JosephCook on 28/08/2022 12:22:46Uhm, your theory sounds interesting, have you tried it?I have used ice/water calorimetry in the past, and as I keep repeating, it is extremely difficult, even with the resources of a national standards laboratory, to do well. To attempt to use it to disprove the most fundamental statement of thermodynamics using domestic kitchen equipment, is beyond foolish.
Uhm, your theory sounds interesting, have you tried it?
Quote from: Bored chemist on 26/08/2022 16:22:11I have to admit the technique isn't really "mine". It was developed by some "famous names".https://www.nature.com/scitable/content/ice-calorimeter-developed-by-lavoisier-and-laplace-14898943/The top side looks uninsulated, which can cause heat leakage.
I have to admit the technique isn't really "mine". It was developed by some "famous names".https://www.nature.com/scitable/content/ice-calorimeter-developed-by-lavoisier-and-laplace-14898943/
I know what a straw man argument is.It's irrelevant.Can you quote the post where you said that you did this experiment properly- well lagged and submerged in well stirred ice and water and told us how you did it and what the results were?
I choose to spend that time to do something more productive.
It won't.Because, that would require the transfer of heat to or from teh ice and, because everything is at the same temperature, there is no impetus to drive the energy from one place to another.Why do you not understand and accept this?Which bit does not make sense to you?
It seems that the energy flow can be driven by gravity through buoyancy and temperature difference.
The ice will be naturally separated from the water through buoyancy.
the top side will gradually become cooler than the bottom side.
Quote from: hamdani yusuf on 30/08/2022 22:36:04It seems that the energy flow can be driven by gravity through buoyancy and temperature difference.You can only use temperature difference to move energy if you actually have a temperature difference.Do you not realise that you ruled that out when you asked "Is there a net heat exchange between water and ice at 0 degree C?"?If it's all at 0C there is no temperature difference.Quote from: hamdani yusuf on 30/08/2022 22:36:04The ice will be naturally separated from the water through buoyancy. Yes, ice floatsQuote from: hamdani yusuf on 30/08/2022 22:36:04the top side will gradually become cooler than the bottom side. How?Where is the energy coming from or going to?What is providing the impetus to drive that energy transfer?
The energy is provided by the environment, because practically, insulations can't be perfect.
So, if a liter of ice-water mixture is in an insulated container, and initially well mixed, the top side will gradually become cooler than the bottom side. The ice will be naturally separated from the water through buoyancy.
which is then propagated to the inner layers.
Which effect is stronger can be shown by an experiment.
Told you so, many times. Which is why you need a continuously-stirred slush. Melting snow is a good start.
Quote from: alancalverd on 01/09/2022 13:30:58Told you so, many times. Which is why you need a continuously-stirred slush. Melting snow is a good start.I'm thinking about circulating the cool water using a small pump, like the one used in aquariums.
I'm thinking about circulating the cool water using a small pump, like the one used in aquariums.
Quote from: hamdani yusuf on 01/09/2022 16:02:52Quote from: alancalverd on 01/09/2022 13:30:58Told you so, many times. Which is why you need a continuously-stirred slush. Melting snow is a good start.I'm thinking about circulating the cool water using a small pump, like the one used in aquariums. Don't forget to allow for the heat it adds.
Do you really not understand that, if you have convection currents your system is not at 0oC?What do you think dives the currents?Did you think it was magic?
To repeat the obvious answer to the original question: No, by definition.
Why do you think I need to use a pump in the first place?
I can use ice blocks held to the bottom of the container using a cage. Slightly warmer water coming down to the bottom will be cooled down by the ice, and flow back up again, producing a natural circulation
Quote from: alancalverd on 02/09/2022 13:23:53To repeat the obvious answer to the original question: No, by definition.How does it help to predict experimental results?