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These appear to be members of a class of minerals called evaporites - formed by evaporation of water from temporary lakes, leaving behind crystals of the minerals that were previously dissolved in the water.- So washing the sand out is probably not a good idea, as that will dissolve some of the mineral back into the water.- Next time try blowing the sand out with a gentle flow of air...See: https://en.wikipedia.org/wiki/Evaporite